原子荧光法测定土壤中砷前处理方法影响因素的研究

针对方法(GB/T 22105.2—2008)中土壤样品前处理过程中影响砷测定结果的因素进行了各类批次实验,得出各种因素对结果的影响程度及其消解的最佳条件。土壤样品的最佳称量范围为0.2～0.6g,消解液加入量的最佳范围为10～15ml,最佳消解时间为2h,硫脲溶液和抗坏血酸溶液的加入量必须满足20～30ml的条件,样品中加入还原剂后,静置时间不得低于20min,通常为30min。     

原子吸收石墨炉技术测定水中痕量阴离子洗涤剂

本文研究了用乙二胺铜(Ⅱ)—氯仿作为络合—萃取体系,石墨炉原子吸收技术间接测定水中痕量阴离子洗涤剂的一种方法。其检出限为2.0ug/1,加标回收率为89.6%～104.5%。具有选择性好、灵敏度高、快速简便等特点。同时还研究了水样的酸度和共存离子对测定的影响。对于用原子吸收进行有机分析具有一定的实际意义。     

TENMILE CREEK: A STUDY OF STREAM RELOCATION1

ABSTRACT: After input from various interested agencies, three miles of creek were relocated to facilitate the construction of Interstate 70 through Tenmile Canyon west of Denver. The 0.5.million dollar project was designed to provide fish habitat of equal value to that present before construction or, if possible, to improve this habitat. Construction techniques were designed to minimize damage to flora and fauna. After the channels were excavated, rock and log fish habitat structures were constructed. Two years after construction, a 4 percent chance flood occurred at the project area which made almost 75 percent of the habitat structures ineffective. Pool-riffle ratios and quantity and quality of spawning areas remained essentially unchanged throughout the period. Population estimates indicated an increase in the number of fish in the postconstruction period compared to preconstruction numbers. Fish biomass estimates for the project area were comparable for the two periods. Aquatic invertebrate populations were unchanged as indicated by comparison of three pre- and postconstruction indices.     

COLD-SHOCK RESISTANCE TO LARGEMOUTH BASS,BLUEGILL, AND CHANNEL CATFISH1

ABSTRACT: Juvenile specimens of largemouth bass, bluegill, and channel catfish were tested to determine their ability to withstand abrupt temperature decreases simulating the environmental impact from a sudden shutdown of a nuclear reactor during the winter. Temperature reductions were administered over 2-hour and 24-hour periods to assess the importance of the rate of temperature change and hence the mitigative value of having a holding pond with a one-day retention time between the proposed cooling tower discharge and the receiving stream. Temperature decreases administered over a 2-hour period resulted in much greater mortality than decreases of the same magnitude administered over a 24-hour period. Thus, the value of a pond for mitigation from cold shock was substantiated. Results also indicated that adherence to the U.S. EPA temperature criteria for freshwater fish should provide adequate protection from cold shock.     

SUBALPINE,COLD CLIMATE,STORMWATER TREATMENT WITH A CONSTRUCTED SURFACE FLOW WETLAND1

The Tahoe City Wetland Treatment System (TCWTS) was constructed in 1997 to treat stormwater runoff from 23 ha of commercial, highway, and residential land use in the Lake Tahoe Basin. This subalpine, constructed, surface flow wetland treatment system consists of two cells in series, with a design water surface area of about 0.6 ha. Water quality monitoring from October 2002 through September 2003 was conducted with autosamplers at the inflow and outflow sites during 24 sampling events, with a median duration of 53 hours, representing 42 percent of total inflow to this wetland during the year. Monitoring data indicate an improvement of 49 percent or greater in effluent concentrations of dissolved phosphorus, nitrate, orthophosphorus, and total suspended solids. On average, event mean concentrations of total phosphorus were reduced from a median 279 μg/l at the inflow to 94 μg/l at the outflow. Event mean concentrations of total nitrogen were reduced from a median 1,599 μg/l at the inflow to 810 μg/l at the outflow. Net nutrient retention for the sampling period was estimated at 3 g phosphorus (P)/m²/y and 13 g nitrogen (N)/m²/y. Almost 4,000 kg of suspended sediment was captured by this wetland system during the year.     

“一一·二四”海难渤海风场的数值模拟

用中尺度数值模式 ＭＭ５对 １９９９年 １１月 ２４日烟台附近发生重大海难事故的渤海风场进行了数值模 拟，探讨了该次冷锋大风的风场特征和影响机制．结果表明：用９０ｋｍ的粗网格可以成功地模拟地面冷高压 与锋面的发展和移动，以及高空环流形势的演变．而通过３０ｋｍ细网格的模拟发现，在冷锋后的行星边界层 中．存在着一条宽度为 ２００ ｋｉｎ的中尺度强风带，最大风速位于 ９２５ｈＰａ，它与高空的极锋急流并不相连；细 网格还模拟出了渤海中尺度低压的发展过程，它使近地面层大风的强度显著加强．模拟还表明，海陆差异对 近地面的风场分布有重要的影响，强风带移入渤海后，在渤海海域形成一个 ２００—３００ ｋｍ的中尺度强风 区．因此，采用具有较高分辨率的中尺度数值模式，对提高渤海大风的预报水平，避兔海难事故的发生更具 有重要意义．     

Dynamics of Bacterial Abundance,Biomass, Activity,and Community Composition in the Oligotrophic Traunsee and the Traun River (Austria)

The holomictic Traunsee is the deepest and second largest lakein Austria. The special characteristic of this ecosystem isthe fact that local salt and soda industries presumably alterthe lake by the discharge of waste materials. Since thebeginning of the 20th century salt and soda works areannually releasing up to 50,000 tons of solid wastes and up to150,000 tons of chloride into Traunsee. To assess potentialeffects of these anthropogenic impacts on the bacterioplanktonthree sampling sites, influenced as well as not influenced bythe industrial discharge, were chosen for comparison andsampled monthly from November 1997 to October 1998. Bacterialabundance ranged between 0.4 to 3.0 × 10⁶ cells ml^-1 with decreasing numbers along the depth profile. Theproportion of actively respiring bacteria, i.e. INT [2-(4-iodophenyl)-3-(4-nitrophenyl)-5-phenyltetrazolium chloride]reducing cells, never exceeded 10% of DAPI (4',6'-diamidino-2-phenylindole) stained cells. Fluorescence in situ hybridization (FISH) was used to examine the seasonal and spatial distribution of dominant phylogenetic groups of thebacterioplankton. Up to 84% of bacteria detected with DAPIcould be detected via FISH applying the universal bacterialprobe EUB338. Percentages of alpha- and beta-Proteobacteriaand members of the Cytophaga-Flavobacterium cluster did notexceed 60% of DAPI-stained cells.Beta-Proteobacteriaappeared to be the most abundant group, not only in Traunsee butalso in two reference lakes, Attersee and Hallstättersee. No significant differences in any of the bacterial parameters couldbe detected between the three sampling sites and all measurementswere found in the range reported for oligotrophic lakes. The highdischarge of the Traun River, resulting in a lake water renewaltime of only one year, may diminish possible effects of industrial waste discharge in the pelagic zone.     

USE OF X-RAY FLUORESCENCE TO DETERMINE TRACE METALS IN WATER RESOURCES1

ABSTRACT. The X-ray fluorescence method was used to analyze trace metals collected in particulate form on filter papers and from the ionic state by ion exchange filter papers. The samples were prepared by allowing water to pass through these filter papers. The procedures necessary for using the X-ray fluorescence method are described. A number of samples were taken from the Great Miami River in Dayton, Ohio over one year showing the presence of the following metals, Ca, Ti, Cr, Fe, Cu, Zn, Sr, and Cd. Elements in the periodic table between Ti and Cs were detectable to a sensitivity limit of the order of 30 ppb for metals in the particulate form and 0.4 ppm for metals in the ionic form.     

AFS-830型双道原子荧光光度计同时测定饮用水中砷、汞

主要探讨应用AFS-830型双道原子荧光光度计，在饮用水监测中同时测定水中砷、汞的方法和技术。此法是在硝酸介质，以硼氢化钠作还原剂，进行原子化，被测元素原子激发出荧光强度值在一定范围内与被测元素的浓度成正比。砷与汞的检出限分别为0．0618和0．0158ug／L。     

省沽油中硒含量及其测定方法研究

采用消化液硝酸／高氯酸消解法、硝酸-硫酸消解法和微波消解方法消化省沽油，用原子吸收分光光度法测定硒（Se）含量。比较了3种消解方法在测定省沽油中的硒含量。发现微波消解法测定野生省沽油（干菜）中Se含量准确性好、时间段效率高、对环境污染少、操作简单。